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Question: Synthesis of iron(III) EDTA complex, Na[Fe(EDTA].3H2O introduction
Synthesis of iron(III) EDTA complex, Na[Fe(EDTA].3H2O, requires knowledge in the field of inorganic and physical chemistry. This synthesis is an excellent exposition of the manipulation of the properties of a metal through complexation. Ethylenediaminetetraacetic acid (EDTA) forms stable complexes with most metal ions, iron(III) included. EDTA is a hexadentate ligand, which means it can donate six pairs of electrons to form coordinate bonds with a metal ion. The iron(III) EDTA complex is therefore an example of a hexadentate complex ion. The process of complexation involves the displacement of water molecules from the hydration sphere of a metal ion by the ligand (EDTA). The preparation of iron(III) EDTA complex commonly involves the reaction of ferric chloride with disodium EDTA in an aqueous solution. The pH of the solution is then adjusted to around 7. This is followed by heating under reflux conditions, eventually producing an orange-yellow solution of the iron(III) EDTA complex. The reaction is generally performed under neutral or slightly basic conditions, as under acidic conditions, the EDTA would protonate and would not be able to bind effectively to the iron(III) ion. It's important to note that safety measures must be observed during the synthesis as both the reactants and the products can be harmful if not handled correctly. Also, like many complexation reactions, the synthesis of iron(III) EDTA complex illustrates important aspects of coordination chemistry that have many implications in various scientific fields, including environmental science, medicine, and analytical chemistry.
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